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What Chemicals Are Used in Cooling Tower Water Treatment

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Effective cooling tower water treatment is essential for maintaining performance, extending equipment life, reducing corrosion, preventing scale and biological growth, and minimizing maintenance costs. Cooling tower water treatment chemicals play a central role in these objectives—especially in systems such as a water cooling tower, water cooling tower system, water cooled tower, and closed loop cooling tower. This article explains the key chemical groups used, how they work, and best practices for their application. It also highlights how quality solutions from manufacturers like Mach Cooling (https://www.machcooling.com/) support optimized water treatment performance.

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Cooling Tower Water Treatment Overview

Cooling towers reject heat through water evaporation. As water recirculates, dissolved minerals, corrosion byproducts, and microorganisms accumulate. Without proper treatment, this leads to:

  • Scale formation (mineral deposits on heat transfer surfaces)

  • Corrosion (metal degradation in piping and equipment)

  • Microbiological growth (biofilm and Legionella risk)

  • Reduced heat transfer efficiency

A well-designed cooling tower water treatment program uses a combination of cooling tower water treatment chemicals tailored to water quality, operating conditions, and tower type (open vs. closed loop).

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Why Water Treatment Chemicals Are Necessary

 Scale Prevention

When hard water evaporates, dissolved minerals (like calcium and magnesium) precipitate and form scale, which impedes heat transfer.

 Corrosion Control

Metal components—including steel, copper, and aluminum—can corrode due to oxygen, conductivity, and aggressive ions in the water. Corrosion inhibitors protect these surfaces.

 Microbiological Control

Warm, recirculating water in cooling towers is an ideal environment for bacteria and algae. Biocides reduce these risks and help prevent biofilms that hinder heat transfer and can harbor pathogens like Legionella.

 Cycles of Concentration Management

“Cycles of concentration” refer to the ratio of dissolved solids in circulating water relative to makeup water. Good chemical treatment allows higher cycles (less blowdown), saving water while controlling scale and corrosion.

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Major Cooling Tower Water Treatment Chemicals

Scale Inhibitors

Scale inhibitors prevent mineral crystals from forming and depositing on heat exchange surfaces. Common chemicals include:

  • Phosphonates

  • Polymeric dispersants (e.g., polyacrylates)

  • Threshold inhibitors

These chemicals bind ions like calcium and magnesium or disrupt crystal growth, reducing scale formation even at higher concentration cycles.


Corrosion Inhibitors

Corrosion inhibitors form a protective film on metal surfaces, reducing oxidation and metal loss. Types include:

  • Azoles (e.g., benzotriazole for copper alloys)

  • Nitrites (for ferrous surfaces)

  • Molybdates

  • Phosphate-based inhibitors

Corrosion inhibitors are especially important in systems that combine different metals (e.g., copper and steel), which can create galvanic corrosion.


Biocides (Microbiological Control)

Biocides control bacteria, algae, and slime. They are typically categorized as:

  • Oxidizing biocides

  • Non-oxidizing biocides

Type Examples Primary Function
Oxidizing Chlorine, chlorine dioxide, bromine Rapid kill of broad spectrum microbes
Non-oxidizing Glutaraldehyde, isothiazolinones, quats Long-lasting control of biofilms and resistant organisms

Biocides are often applied intermittently (shock dosing) or continuously at low levels.


Dispersants

Dispersants keep suspended solids and sludge in suspension so they can be removed by blowdown. Common dispersants include:

  • Polyacrylic acids

  • Sulfonated polymers

These chemicals help prevent fouling and maintain efficient heat transfer surfaces.


 Additional Chemical Agents

pH Adjusters

Maintaining a stable pH (typically 7–8.5) helps optimize the performance of other chemicals and reduces corrosion. Common agents:

  • Sodium hydroxide (raises pH)

  • Sulfuric or hydrochloric acid (lowers pH)

Anti-Foaming Agents

Foam can develop due to organics or entrained air. Anti-foaming agents (silicone or organic compounds) reduce foam formation.

Chelating Agents

Chelants (like EDTA or citrates) bind metal ions, preventing them from participating in scale formation or corrosion reactions.


 Chemical Treatment by Cooling Tower Type

Water Cooling Tower & Water Cooled Tower

In open systems like a water cooling tower or water cooled tower, evaporation leads to rapid concentration of dissolved solids. Typical treatment includes:

  • Scale inhibitors

  • Corrosion inhibitors

  • Oxidizing and non-oxidizing biocides

  • Dispersants

Due to higher evaporation rates and blowdown requirements, these systems often require robust chemical monitoring and control.


 Closed Loop Cooling Tower

Closed loop cooling towers circulate water inside a heat-exchange coil separated from the air stream. Although direct exposure to contaminants is reduced, treatment is critical to prevent scale on coil surfaces.

Closed-loop treatment focuses on:

  • Scale inhibitors (to protect heat exchanger surfaces)

  • Corrosion inhibitors (to prolong tubing life)

  • pH control agents

Biocides may be used if any open recirculation or makeup water quality issues arise.

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How Chemicals Are Applied

 Batch vs. Continuous Dosing

Chemicals may be dosed in two main ways:

  • Batch dosing: Periodic addition of concentrated chemicals.

  • Continuous dosing: Small, consistent feed using chemical metering pumps.

Continuous dosing provides more stable control and often reduces overall chemical usage.

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 Monitoring and Control

Water treatment effectiveness is monitored through:

  • pH measurement

  • Conductivity / TDS

  • Oxidation-Reduction Potential (ORP)

  • Bacteria counts (e.g., ATP testing)

  • Langelier Saturation Index (LSI) for scale potential

Automated controllers can integrate sensors with chemical feed pumps, improving responsiveness and consistency.


 Typical Cooling Tower Water Treatment Chemical Table

Chemical Type Purpose Common Examples
Scale Inhibitors Prevent mineral deposits Phosphonates, polyacrylates
Corrosion Inhibitors Protect metals Azoles, nitrites, molybdates
Oxidizing Biocides Broad microbial control Chlorine, bromine
Non-oxidizing Biocides Biofilm control Glutaraldehyde, isothiazolinones
Dispersants Prevent particle buildup Polyacrylic acids
pH Adjusters Maintain stable pH Acids & bases
Anti-Foam Agents Reduce foam Silicone org. compounds

 Common Challenges and Solutions

 Scaling

Cause: High hardness or silica.
Solution: Use strong scale inhibitors and dispersants; adjust blowdown to manage cycles of concentration.

 Corrosion

Cause: Low pH, high chloride, oxygen ingress.
Solution: Corrosion inhibitors, oxygen scavengers (e.g., sulfites), pH control.

 Microbial Growth

Cause: Warm temperatures, nutrients in water.
Solution: Combined oxidizing and non-oxidizing biocide program; regular monitoring.


 Best Practices for Cooling Tower Water Treatment

Customized Treatment Plans

Every system—including water cooling tower system and closed loop cooling tower installations—has unique water quality and loading. Treatment should be tailored to makeup water chemistry, heat load, and environmental regulations.


Regular Monitoring and Adjustment

Monitor pH, conductivity, ORP, and microbial indicators frequently. Automated systems improve consistency and reduce human error.


 Integrate with Operational Controls

Good treatment integrates with blowdown scheduling, conductivity control, and maintenance routines.


 How Mach Cooling Supports Water Treatment

Manufacturers like Mach Cooling (https://www.machcooling.com/) provide more than just equipment—they support comprehensive cooling tower water treatment strategies by offering:

  • Expert guidance on cooling tower water treatment chemicals selection

  • Engineering support for integrating treatment systems with cooling towers

  • Turnkey solutions for water cooled tower and closed loop cooling tower projects

Effective treatment improves heat rejection, reduces operating cost, and extends equipment service life.


Conclusion

Proper use of cooling tower water treatment chemicals is vital for maintaining performance in any cooling system. From scale inhibitors and corrosion control agents to biocides and dispersants, each chemical group addresses specific challenges related to water quality and heat transfer. A well-designed treatment program helps:

  • Control scale and corrosion

  • Prevent biological growth

  • Improve heat transfer and efficiency

  • Extend the life of the water cooling tower system

Partnering with experienced suppliers like Mach Cooling strengthens operational reliability and ensures your cooling systems run efficiently and sustainably.



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